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Magnetism

Factors Determining Magnetic Response

Moving or spinning electrical charges such as electrons create a magnetic field with N and S poles. If most of the poles are aligned in the same direction, the material is magnetic. The factors that determine the way a material responds to a magnetic field are the alignment of electrons in the atom, of the atoms in a molecule or alloy, and the domains within the material.

Since the atoms or molecules need to be aligned, gases and liquids are typically not magnetic, because of the free motion of the particles. There are some exceptions, especially concerning the plasma state of matter. Typically, all magnets are solid metals.

Questions you may have include:

  • What are electron orientation factors?

  • What are molecule factors?

  • What are domain factors?

Moving electrons create magnetic field

When electrons move, they create a magnetic field. Placing a compass near a wire carrying DC electrical current can show that a magnetic field is created. The field is also created when electrons rotate around a nucleus and when they spin while in orbit.

Spinning electrons

Electrons have a property called spin. This spinning creates a magnetic field with N and S poles, just as the spinning Earth has magnetic poles. Note that the N pole on an electron is really a North-seeking pole, just as in a magnet.

If electrons in the shells of an atom spin in the same direction, the atom will exhibit a magnetic field and will respond to the forces of a magnet. If half of the electrons spin one way and the rest spin the other way, they will neutralize each other and the material will not be affected by a magnetic field

This atom is barely magnetic because all its electrons are not aligned

Atoms such as iron have most of their electrons aligned in the same direction. Thus, iron or nickel would be attracted to a magnet. An element with half of its electrons oriented one way would not be attracted to a magnet.

Rotation around nucleus

In the Bohr--or solar system--model of an atom, the electrons orbit around the nucleus. This motion also creates a magnetic field. The atom will have N and S poles, but the orientation of the electrons will determine whether the atom has a strong magnetic field or weak field.

Molecular alignment

If atoms having a strong magnetic field are aligned within a molecule, it too will be magnetic. If atoms are facing different directions, their fields will cancel out each other.

Although some atoms may be highly magnetic, they really need to be aligned to make a material magnetic. If two or more elements are chemically combined to form a molecule, it is quite possible that the compound is not very magnetic, because the orientations of the atoms in the molecule work against each other. A good example of this is to compare the magnetic properties of iron as compared to its compounds if iron oxide (rust) and iron sulfide.

Alloys

Metals of different elements can be mixed when they are in the molten or liquid state to form alloys. These combinations result in materials with slightly different physical and chemical properties than the elements by themselves.

If the metals typically respond well to a magnetic field--such as iron and nickel--then their alloy has even a stronger reaction to magnetism. On the other hand, there are some alloys of iron--such as forms of stainless steel--that do not respond well at all to a magnet.

Domains

The final factor in a material being magnetic concern the orientation of its domains. A group of atoms in a metal may become aligned, but the various groups may be misaligned. These groups are called domains.

It is necessary to line up many of the domains in a material like iron in order for it to become a magnet.

Magnetic material with domains misaligned

Aligned domains makes material highly magnetic

In conclusion

Alignment of electrons, atoms, and domains are important in determining the magnetic response of a material and whether it is a magnet. Since the atoms or molecules need to be aligned, gases and liquids are typically not magnetic, and most magnets are solid metals.





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